Abstract
In this work, the solubility and diffusivity of nitrous oxide (N 2 O) in aqueous 4-(diethylamino)-2-butanol (DEAB) solutions were measured. Solubility was measured in a stirred cell reactor over the temperature range of 298–343 K and concentration range of 0.68–3.77 M. On the other hand, diffusivity was measured in a laminar jet absorber over the temperature range of 298–318 K and concentration range of 1.0–2.5 M. An attempt was made to correlate the solubility data with well-known models (semiempirical model, Redlich–Kister equation, and polynomial model). It was observed that only the polynomial model correlated the solubility of N 2 O in aqueous DEAB solution satisfactorily with an AAD of 0.1%. Similarly, an attempt was made to correlate the diffusivity data with well-known models (semiempirical model and modified Stokes–Einstein model). The semiempirical model provided better predicted N 2 O diffusivity data compared with the experimental data with an AAD of 3.4%. These data can then be used to determine the physical solubility and physical diffusivity of carbon dioxide (CO 2 ) in aqueous DEAB solutions using the “N 2 O analogy”.
Publication details
- Authors: Sema, T., Edali, M., Naami, A., Idem, R., Tontiwachwuthikul, P.
- Published in: (2012) Industrial and Engineering Chemistry Research, 51 (2), pp. 925-930.
- Year: 2012
- DOI: 10.1021/ie200832c